[EN] Subphthalocyanine has been incorporated into a robust metal-organic framework having amino groups as binding sites. The resulting SubPc@MIL-101(Cr)-NH2 composite has a loading of 2 wt%. Adsorption of subphthalocyanine does not deteriorate host crystallinity, but decreases the surface area and porosity of MIL-101(Cr)-NH2. The resulting SubPc@MIL-101(Cr)-NH2 composite exhibits a 575 nm absorption band responsible for the observed photoredox catalytic activity under simulated sunlight irradiation for hydrogenative dehalogenation of alpha-haloacetophenones and for the coupling of alpha-bromoacetophenone and styrene. The material undergoes a slight deactivation upon reuse. In comparison to the case of phthalocyanines the present study is one of the few cases showing the use of subphthalocyanine as a photoredox catalyst, with its activity derived from site isolation within the MOF cavities. Financial support from the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and RTI2018-098237-B-C21) and Generalitat Valenciana (Prometeo 2017-083) is gratefully acknowledged. S. N. is thankful for the financial support from the Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016), the Ministerio de Ciencia, Innovacion y Universidades RTI 2018-099482-A-I00 project and the Generalitat Valenciana grupos de investigacion consolidables 2019 (ref: AICO/2019/214) project. S. R.-B. also thanks the Research Executive Agency (REA) and the European Commission for the funding received under the Marie Sklodowska Curie actions (H2020-MSCA-IF-2015/Grant agreement number 709023/ZESMO). Santiago-Portillo, A.; Remiro-Buenamañana, S.; Navalón Oltra, S.; García Gómez, H. (2019). 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Subphthalocyanine encapsulated within MIL-101(Cr)-NH2 as a solar light photoredox catalyst for dehalogenation of alpha-haloacetophenones

Abstract