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Influence of the aerosol solar extinction on photochemistry during the 2010 Russian wildfires episode
In this work, impact of aerosol solar extinction on the photochemistry over eastern Europe during the 2010 wildfires episode is discussed for the period from 5 to 12 August 2010, which coincides to the peak of fire activity. The methodology is based on an online coupling between the chemistry-transp...
Primary marine aerosol physical flux and chemical composition during a nutrient enrichment experiment in mesocosms in the Mediterranean Sea
International audience While primary marine aerosol (PMA) is an important part of global aerosol total emissions, its chemical composition and physical flux as a function of the biogeochemical properties of the seawater still remain highly uncharacterized due to the multiplicity of physical, chemica...
Silicon particles as trojan horses for potential cancer therapy
Cyclopentadienyl pyridazines, oxazines, and thiophenes and their applications in energy and advanced electronics
Due to their unique properties including environmental stability, high processibility, and low production cost, organic-based electronic materials are an attractive alternative to conventional inorganic semiconductors for use in advanced electronic applications. The growing interest and demand for r...
Regio-directed synthesis of a ZnIIFeIII complex from an unsymmetrical ligand and its relevance to purple acid phosphatases.
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An Alternative to Static Climatologies: Robust Estimation of Open Ocean CO2 Variables and Nutrient Concentrations From T, S, and O-2 Data Using Bayesian Neural Networks
This work presents two new methods to estimate oceanic alkalinity (A(T)), dissolved inorganic carbon (C-T), pH, and pCO(2) from temperature, salinity, oxygen, and geolocation data. "CANYON-B" is a Bayesian neural network mapping that accurately reproduces GLODAPv2 bottle data and the biogeochemical...
Novel layered organic-inorganic hybrid materirals with bridged silsesquioxanes as Pillars
δ 15N measurement of organic and inorganic substances by EA-IRMS: a speciation-dependent procedure
Little attention has been paid so far to the influence of the chemical nature of the substance when measuring δ 15N by elemental analysis (EA)-isotope ratio mass spectrometry (IRMS). Although the bulk nitrogen isotope analysis of organic material is not to be questioned, literature from different di...
Unravelling Platinum-Zirconia Interfacial Sites Using CO Adsorption
Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides
S Ley, S. V., & Thomas, A. W. (2003). Moderne Synthesemethoden: Kupfer-vermittelte C(Aryl)-O-, C(Aryl)-N- und C(Aryl)-S-Verknüpfungen. Angewandte Chemie, 115(44), 5558-5607. doi:10.1002/ange.200300594 Surry, D. S., & Buchwald, S. L. (2008). Biarylphosphanliganden in der palladiumkatalysierten Aminie...
Inhibitory Effect of Azamacrocyclic Ligands on Polyphenol Oxidase in Model and Food Systems
The annual and seasonal variability of the carbonate system in the Bay of Brest (Northwest Atlantic Shelf, 2008–2014)
From 2008 to 2014, the MAREL-Iroise buoy, located in the Bay of Brest, collected high -frequency measurements of partial pressure of CO2 (pCO(2)) and ancillary hydrographic parameters, in conjunction with a comprehensive sampling regime of two additional carbonate system variables total alkalinity (...
Development and Characterization of Polyester and Acrylate-Based Composites with Hydroxyapatite and Halloysite Nanotubes for Medical Applications
Unravelling the crystal structure of Nd5.8WO12-delta and Nd5.7W0.75Mo0.25O12-delta mixed ionic electronic conductors
S Gozzo, F., Cervellino, A., Leoni, M., Scardi, P., Bergamaschi, A., & Schmitt, B. (2010). Instrumental profile of MYTHEN detector in Debye-Scherrer geometry. Zeitschrift für Kristallographie, 225(12), 616-624. doi:10.1524/zkri.2010.1345 Scherb, T. (2011). PhD thesis, Technische Universität Berlin,...
Metal organic frameworks as catalysts in solvent-free or ionic liquid assisted conditions
S Furukawa, H., Müller, U., & Yaghi, O. M. (2015). «Heterogeneity within Order» in Metal-Organic Frameworks. Angewandte Chemie International Edition, 54(11), 3417-3430. doi:10.1002/anie.201410252
Amidase-responsive controlled release of antitumoral drug into intracellular media using gluconamide-capped mesoporous silica nanoparticles
Molecular models of natural organic matter and its colloidal aggregation in aqueous solutions: Challenges and opportunities for computer simulations
Natural organic matter (NOM) is ubiquitous in soil and groundwater and its aqueous complexation with various inorganic and organic species can strongly affect the speciation, solubility and toxicity of many elements in the environment. Despite significant geochemical, environmental and industrial in...
Reusing Geopolymer Waste from Matrices Based on Metakaolin or Fly Ash for the Manufacture of New Binder Geopolymeric Matrices
International audience The increasing use of geopolymer materials in the construction and civil engineering sectors generates a large amount of non-biodegradable waste that will end up in landfills. It is therefore necessary to anticipate solutions for the proper management of this waste. In this wo...
Embedding catalytic nanoparticles inside mesoporous structures with controlled porosity: Au@TiO2
A reactive transport model of CO2-water-rock interaction in a push-pull test in basaltic rocks
Basaltic rock formations have been proposed as suitable hosts for CO2 storage. Basalts have a high content in silicate minerals, Ca and Mg, which neutralize the acidic CO2 injected solution. Moreover, under such conditions the formation of stable carbonate minerals, which is the safest way to store...
Thin magazine interview Profa. Flaviana Tavares (UFVJM)
A Profa. Flaviana Tavares é graduada em Ciências Naturais e Licenciada em Química. Mestre em Agroquímica. Doutora em Química Inorgânica. Professora da UFVJM desde 2009. Nessa entrevista, a Profª. Flaviana Tavares fala sobre um tema importantíssimo para o ensino superior: a retenção e a evasão. A ent...
EDUCATIONAL AND METHODICAL COMPLEX OF CHAIR IN CHEMISTRY
The article differentiates the concept of an educational data set for a separate educational program and the concept of an educational and methodical complex of a chair. The contents of available educational complexes in chemistry is considered. The article analyzes the reasons of complexes lack and...
UBA000168296 — Vriesland Large Placate and Charter Book: Part Two.
Titel: Groot placaat en charter-boek van Vriesland:Tweede deel . Publisher: Willem Coulon Place: Leeuwarden Year: 1773 Used version: The copy we used for the transcriptions is held at Amsterdam University Library and digitised by the KB National Library of the Netherlands. Link digitised version of...
Students’ Mastering of Structural Analysis of Substance as a Method to Form Future Specialists’ Scientific Thinking. Part II
Introduction. In today’s knowledge society, the amount of scientific-applied information, which university graduates have to acquire, continues to increase continuously. There is a concurrent reduction in the number of study hours to undertake educational programmes in order to increase the hours fo...
Students’ Mastering of Structural Analysis of Substance as a Method to Form Future Specialists’ Scientific Thinking. Part I
Introduction. In today’s knowledge society, the amount of scientificapplied information, which university graduates have to acquire, continues to increase continuously. There is a concurrent reduction in the number of study hours to undertake educational programmes in order to increase the hours for...